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ActiveTcl can run starkits. Also, the built-in tclsh with recent MacOS X releases (10.3 and after? 10.4] includes awareness of starkits (more precisely, it successfully "package require starkit").
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assoc .kit .kit=kitfile ftype kitfile kitfile="c:\...\tclkit.exe" "%1" %*
(just moved the line assoc to position 1)
See also: